The present dissertation deals with variable stress patterns in English complex adjectives such as celebratory, identifiable or imaginative. This variation is usually described in terms of retaining the stress from the embedded base (idéntify -> idéntifiable) or deviating from the stress of the embedded base (idéntify -> identifíable). While several accounts have explored this variation, none of them have been able to identify a plausible reason for why it occurs. Additionally, the role of individual speaker differences has been disregarded in the discussion. This dissertation therefore explores the empirically observable extent of the variation and investigates possible causes of it with a special focus on individual differences between speakers. It uses data from a complex online experiment that included five different tasks to assess speakers' stress production, perception, morphological processing, vocabulary size and other factors. It furthermore tests the predictions of previous accounts on the large set of authentic utterances from speakers collected using this online experiment. The data show that individual differences in vocabulary size between speakers are a significant predictor of a speaker's tendency to retain the stress of the embedded base.

Knapp 90 Jahre nach Erscheinen des Buchs von Paul Graindor zu den „Bustes et Statues-Portraits d'Egypte Romaine“ widmet sich mit der vorliegenden Dissertation erstmals wieder eine monographische Studie der marmornen Bildnisplastik der römischen Provinz Aegyptus von ihrer Gründung im Jahr 30 v. Chr. bis zum Ende des 3. Jhs. n. Chr. Basierend auf einer umfassenden Zusammenstellung bekannter, aber auch bislang unpublizierter Portraits sowie einer Neudokumentation zahlreicher Objekte gelingt erstmalig eine belastbare chronologische und typologische Auswertung dieser Bildnisse. Zwar bilden dabei die Darstellungen aus weißem Marmor die zentrale und auch quantitativ bei weitem größte Materialgruppe, doch es finden auch Bildnisse aus anderen Werkstoffen wie Bronze, Kalkstein, Gips oder Alabaster Berücksichtigung. Da die Provinz aufgrund geringer eigener Marmorvorkommen fast ausschließlich auf Importe angewiesen war, sind die Marmorbildnisse ein exzellentes Forschungsobjekt, um nicht nur den Handel von Marmor nach Ägypten und seine Distribution und Weiterverarbeitung in der Provinz zu untersuchen, sondern auch damit verbundene handwerkliche Besonderheiten, wie die häufig zu beobachtenden Ergänzungen mit Stuck- oder Steinelementen. Darüber hinaus werden auch Überlegungen zur Semantik des Materials sowie der Herkunft und dem Selbstverständnis der dargestellten Personen angestellt.

Extracellular enzymes in microbial communities play a central role in nutrient cycling and the degradation of (pollutant) substances in various natural and anthropogenic systems. Bound in aquatic biofilms, sludge aggregates, or even unbound at their interfaces, they are of great importance for both the environment and human health. In particular, in wastewater treatment plants and inland waters, hydrolytic activities influence the wide-reaching efficiency of nutrient removal and self-purification, thus contributing significantly to overall water quality. The main goal of this dissertation project was to investigate the factors that influence enzymatic activity and the health of microbial communities in activated sludge and river systems, particularly in relation to anthropogenic influences and natural environmental conditions. The aim was to contribute to a better understanding of the sensitivity of our freshwater ecosystems and to support the long-term preservation of water quality and ecological stability. The development and optimization of appropriate methods, as well as their testing and applicability, were the focal points. For this purpose, a fluorometric microplate assay was developed and adapted to determine both extracellular enzyme activities (EEAs) in activated sludge samples and in intact biofilms. Its suitability for field studies was subsequently tested. Inhibition and activity of selected hydrolases under different conditions were investigated to better understand the mechanisms and potential environmental risks posed by anthropogenic influences and seasonal fluctuations of hydrochemical and climatic parameters. The first phase of the doctoral thesis involved studies on the inhibition of alkaline phosphatase in activated sludge by oxyanions. Using the fluorometric microplate assay, the inhibitory effect was sensitively detected over a pH range of 7.0 to 8.5. IC50- and IC20-concentrations were calculated from modeled dose-response functions. It was found that vanadate and tungstate caused strong inhibitory effects, while molybdate moderately inhibited the enzyme. An increasing pH led to a reduction in the inhibitory effect of tungstate and molybdate. The inhibition effects of vanadate were not significantly affected by the pH. In municipal wastewater, the concentrations of such metal ions are usually low, but industrial wastewater may have pollutant loads that can significantly impact the removal of phosphorus-containing compounds, and thus the efficiency of treatment plants. In the second phase, an attempt was made to further adapt the developed methodology to investigate EEA and kinetics in intact freshwater biofilms. Four different types of bead materials (lava, glass, sintered quartz, and ceramics) fitting into a 96-well microplate were tested as carriers for biofilms on both the laboratory and field scale. The analysis included a total of seven hydrolases as representatives of key nutrient cycles such as phosphorus, carbon, and nitrogen: phosphatases, glucosidases, peptidases (two different types), and sulfatase. Experiments with increasing substrate concentrations led to classical kinetic profiles according to the Michaelis-Menten mechanism. This allowed for the prediction of the biofilm enzymes’ response to different substrate concentrations. Parameters such as Vmax and Km could be derived from the modeled curves. Ceramic beads are particularly suitable for long-term studies due to their high stability, while sintered quartz beads should be preferred for the use in stagnant media (material loss under turbulent conditions). Lava and glass beads, on the other and, proved suboptimal for uniform biofilm development due to their surface properties. The potential use of this fast and sensitive test for ecotoxicological or even human-toxicological studies was demonstrated by the effects of caffeine on the activity of PDE. The result of this part of the research represents a powerful tool for assessing environmental pollution and monitoring water quality. The high application potential was clearly highlighted in the final phase of the project. The goal here was to deepen the understanding of interactions between seasonal factors, anthropogenic influences, and biofilm processes in rivers by investigating EEA and biofilm parameters such as biomass and relating them to hydrochemical and climatic factors. Ceramic beads were exposed both upstream and downstream of a wastewater treatment plant discharge and sampled over a period of seven months. EEAs and biomass varied depending on the season and location, with higher microbial activity observed upstream in winter. Winter conditions led to the dilution of most nutrients as well as in an increse of dissolved oxygen. Nutrient concentrations analyzed downstream were significantly higher in the summer. Accumulation of nutrient or pollutants during the summer months cannot be excluded, which may have led to a general reduction in enzyme activities. Potential causes could be inhibitory effects on the enzymes, or a reduced enzyme activity due to a sufficiently high nutrient supply. In general, the sampling site upstream showed a more pronounced seasonal dynamics, with a significant proportion of the variance in biological parameters (activity and biomass) attributable to seasonal factors. A secondary component, likely reflecting the impact of the treatment plant discharge, explained another portion of the data variance. Regardless of the season, high correlations between biological parameters were observed upstream, while downstream the data were more decorrelated. This could be because the biofilms, under chronic stress, respond less dynamically to seasonal fluctuations. This dissertation illustrates that in addition to anthropogenic stress factors, seasonal fluctuations of hydrochemical and climatic parameters should also be considered in "stress downstream the pipe" studies. The selected methods are recommended for explaining and considering the data variance, as they highlight the complex interplay between microbial enzymatic activity, environmental factors, and pollutants in the activated sludge of wastewater treatment plants and also in aquatic systems. The novel bead assay could pave the way for the future standardization of effect-oriented studies on intact aquatic biofilms.

Die Verfügbarkeit von ortho-Phosphat (o-PO₄) trägt wesentlich zur Eutrophierung von Fließgewässern bei und gefährdet damit das Erreichen des „guten ökologischen Zustands“ gemäß der EU-Wasserrahmenrichtlinie. Da die kommunalen Kläranlagen zentrale Eintragsquellen darstellen, gewinnt die Reduktion von o-PO₄ an dieser Stelle an Bedeutung. Neben der chemischen Phosphorelimination bietet insbesondere die vierte Reinigungsstufe, primär zur Entfernung von Mikroschadstoffen konzipiert, einen Synergieeffekt mit potenziellen Phosphorentfernungsraten von bis zu 85 %. Zur Bewertung des Einflusses einer solchen Reinigungsstufe wurde ein Modell für ausgewählte saarländische Oberflächenwasserkörper (OWK) entwickelt, das den Trockenwetterfall als eutrophierungsrelevantes Szenario abbildet. Ein zentraler Bestandteil ist ein neu erarbeiteter Retentionsansatz, der biochemische und physikalische Prozesse wie Adsorption, Sedimentation und biologische Assimilation berücksichtigt. Auf Basis der Differenz zwischen emissionsseitig bilanziertem und gemessenem o-PO₄-Gehalt wurden für jeden OWK Verminderungsraten je Fließmeter abgeleitet und schließlich eine Gleichung zur Abschätzung der Retention in Abhängigkeit der Einzugsgebietsgröße formuliert. Die Validierung zeigt hinreichende Modellgenauigkeit, wenngleich negative Frachtdifferenzen in einigen Gewässern auf zusätzliche, nicht eindeutig quantifizierbare Einträge – etwa aus Landwirtschaft oder Kanalverlusten – hindeuten. Die Szenarienanalyse belegt, dass eine vierte Reinigungsstufe grundsätzlich zur Reduktion von o-PO₄ an den Messstellen beiträgt. Eine Unterschreitung des geltenden Orientierungswertes wird jedoch nur erreicht, wenn sämtliche Kläranlagen eines OWK nachgerüstet werden – und auch dann nur in einigen Fällen. Damit stellt die vierte Reinigungsstufe allein keine ausreichende Alternative zu den Maßnahmen des 3. Bewirtschaftungsplans des Saarlandes dar, kann jedoch als ergänzende Strategie zur Verringerung der Phosphoreinträge dienen.

Bilevel problems are optimization problems for which parts of the variables are constrained to be an optimal solution to another nested optimization problem. This structure renders bilevel problems particularly well-suited for modeling hierarchical decision-making processes. They are widely applicable in areas such as energy markets, transportation systems, security planning, and pricing. However, the hierarchical nature of these problems also makes them inherently challenging to solve, both in theory and in practice. In this thesis, we study different nonlinear problem settings for the nested optimization problem. First, we focus on nonlinear but convex bilevel problems with purely integer variables. We propose a solution algorithm that uses a branch-and-cut framework with tailored cutting planes. We prove correctness and finite termination of the method under suitable assumptions and put it into context of existing literature. Moreover, we provide an extensive numerical study to showcase the applicability of our method and we compare it to the state-of-the-art approach for a less general setting on suitable instances from the literature. Furthermore, we discuss challenges that arise when we try to generalize our approach to the mixed-integer setting. Next, we study mixed-integer bilevel problems for which the nested problem has a nonconvex and quadratic objective function, linear constraints, and continuous variables. We state and prove a complexity-theoretical hardness result for this problem class and develop a lower and upper bounding scheme to solve these problems. We prove correctness and finite termination of the proposed method under suitable assumptions and test its applicability in a numerical study. Finally, we consider bilevel problems with continuous variables, where the nested problem has a convex-quadratic objective function and linear constraints. We reformulate them as single-level optimization problems using necessary and sufficient optimality conditions for the nested problem. Then, we explore the family of so-called P-split reformulations for this single-level problem and test their applicability in a preliminary numerical study.

Perennial crops eliminate soil disturbance and reduce the amount of synthetic chemicals that are applied to the soil, improving soil biodiversity and food web structure. Additionally, perennial cropping is characterised by all year-round surface coverage which benefits soil biota in terms of habitat and food sources. Perennial intermediate wheatgrass (Thinopyrum intermedium, IWG) was domesticated and commercialised by The Land Institute in Kansas as Kernza® and serves as an example for these nature-based solutions. It develops an extensive root system that has a higher nutrient retention, possibly reducing nutrient runoff. It thereby follows a more resource-conservative strategy with improved belowground-oriented resource allocation in its root system. This may reduce the need for excessive fertiliser as the crop has a higher nitrogen efficiency, among other things. IWG promoted the earthworm community and its diversity, more specifically, the occurrence of epigeic species (litter inhabitants), since those species benefit from the increased soil coverage and elimination of disturbances in the soil. As IWG creates a dense and extensive root system, as shown by the increased occurrence of root-feeding nematodes, endogeic species (horizontal burrowers) are supported through the provision of a reliable food source. IWG was characterised as a mostly undisturbed system with a highly structured food web through nematode analysis, as expressed through the promotion of structure indicators, for example, that are sensitive to disturbances in the soil and are therefore supported under no-till management. The root microbiome is continuously being shaped by the host as the crop regrows from the roots each vegetation period. This creates a symbiotic relationship and a beneficial feedback loop for the crop. Resultantly, the root-endophytic microbiome under IWG had a higher network complexity, connectivity and stability compared to annual wheat. The regrowth from the roots for IWG requires increased nutrient and energy storage, which was indicated by increased starch values. Correspondingly, the longer residence time of the roots in the soil resulted in higher lignin values. Furthermore, the decomposition pathway was dominated by fungivorous nematodes which may correspond to stimulated nutrient cycling and a heterogeneous resource environment, as seen for low input systems. Overall, perennial wheat cultivation improved soil biodiversity already after an establishment of 3-6 years. As those benefits were present for all three countries, the varying soil and climate conditions do not seem to interfere with the positive effect of perennial wheat on the soil ecosystem, demonstrating a wide transferability and adaptability of the crop onto other study sites as well. Enhanced complexity and connectivity of the food web in comparison to annual wheat may indicate a resistance against abiotic stress, suggesting IWG cultivation as a viable option for a sustainable and resilient agriculture. The improvement in nutrient cycling and the resource-efficient cultivation strategy for IWG could enable cultivation on marginal land where annual crop cultivation is not possible as the soils are susceptible to erosion and nutrient runoff. This opens up new possibilities for agricultural cultivation on previously unused land, thus contributing to food security in the future.

Social virtual environments allow their users to meet and collaborate in a shared three-dimensional space, even when far apart from each other in the real world. Within these spaces, the appearance and interaction capabilities of both users and environments can be adapted and changed in a myriad of ways. To enable virtual environments to fulfill their potential of supporting a wide variety of collaboration use-cases, both the impacts of basic interaction design decisions and the individual needs of specific usage areas need to be explored further. This thesis approaches this topic in two ways. First, the basic building blocks of collaboration in social virtual environments are explored by asking the question: "How can social virtual spaces that allow interaction beyond real-world constraints utilize the potential of mutual assistance and shared workflows between multiple users?". Going into further detail for a serious use-case in which direct collaborative interactions and their effect on the included users are especially important, it then explores the potential of collaborative virtual spaces in the therapy domain by asking "How can the potential of social virtual spaces be utilized to support and improve therapy encounters?" With regards to the first research question, the thesis presents two theoretical frameworks detailing different aspects of supporting smooth and varied collaboration processes. In addition, several user studies on the topic of collaborative virtual interaction are described, focusing on the role that different users can play during shared interaction and the effects that this distribution of roles and responsibilities has on both the performance and experience of the involved user pairs. The results presented for this first research question show that social virtual spaces have the potential to provide dedicated support for collaborative workflows. To enable users to adapt their working mode individually and as a team, interaction techniques should complement a team's natural interaction and communication. When presenting novel interactions to users, providing them with a way to support each other can ease their adaptation to these interactions. In these cases, the inclusion of all interested collaborators as active participators should be prioritized in order to let all users benefit from being immersed in a virtual environment. Addressing the combination of social virtual spaces with therapy in relation to the second research question, this thesis presents the result of a series of interviews with practicing physio- and psychotherapists. Motivated by the recorded expert feedback, it also reports on two more detailed explorations of specific areas of interest. The work presented for the second research question demonstrated the promise of using virtual environments in both exercise- and conversation-based therapy practice. Investigating the potential of shared interactions, the exploration of virtual recordings and the adaptation of virtual appearances, the presented work uncovered several topic areas that could be further explored regarding their possible use in the treatment of patients. Taken together, the six research articles presented in this thesis show both the value of supporting and understanding shared interactions in virtual spaces and their potential place in serious use-cases like the therapy domain. When introducing shared virtual environments to new user groups, the opportunity for mutual support through shared interaction techniques could be a crucial building block towards making virtual spaces both accessible and attractive to a variety of users.

Das Thema des Erlebnisses steht bereits seit langem im Fokus von Anbietern von Dienstleistungen. Dies gilt insbesondere für den Tourismus, einer Branche, deren Produkte zu einem signifikanten Teil aus solchen bestehen. Entsprechend der Prominenz des Themas, vor allem in den Bereichen touristischer Produktentwicklung und Marketing, ist dieses bereits breit in der Forschung diskutiert worden. Trotz ausgiebiger Publikationsaktivitäten ist der tatsächliche Wissensstand in diesem Thema dennoch auffällig gering. Ein wichtiges Problem liegt darin begründet, dass die Terminologie im Bereich von Erlebnissen noch nicht allgemein akzeptiert und scharf abgegrenzt ist. So muss zwischen Erlebnissen und Erfahrungen unterschieden werden. Erstere treten während des Prozesses der Wahrnehmung einer touristischen Dienstleistung auf und bilden die Basis für Erfahrungen, welche prägend hinsichtlich der Wahrnehmung wirken und im Gesamtkontext der Reise betrachtet werden. Dieser Unterscheidung wird nicht nur in der englischsprachigen Literatur, in der beide Begriffe mit dem Begriff Experience beschrieben werden, sondern auch in der deutschsprachigen Literatur zumeist zu wenig Rechnung getragen, was dazu führt, dass häufig zu Erlebnissen publiziert wird, obwohl eigentlich Erfahrungen beschrieben werden. Problematisch ist dies vor allem, weil damit ein Phänomen untersucht wird, dessen Basis nahezu gänzlich unbekannt ist. Wichtige Fragen, welche zum Verständnis von Erlebnissen und damit auch von Erfahrungen bleiben unbeantwortet: 1) Welche Faktoren werden in der Genese von Erlebnissen wirksam? 2) Wie wirken diese zusammen? 3) Wie wird die Stärke eines Erlebnisses determiniert? 4) Wie werden Erlebnisse stark genug um den Konsum einer touristischen Dienstleistung zu prägen und damit gegebenenfalls zu Erfahrungen zu werden? In der vorliegenden Arbeit wurden diese Fragen beantwortet, womit ein erster Schritt in Richtung der Füllung einer für die Tourismuswissenschaft nicht unbedeutenden Forschungslücke gelungen ist. Um Erlebnisse, den Prozess der Genese dieser und deren Bewertung durch den Gast verstehen zu können, wurde ein triangulierter, zweistufiger Forschungsprozess ersonnen und in einem naturtouristischen Setting im Nationalpark Vorpommersche Boddenlandschaft zur Anwendung gebracht. Es handelt sich dabei um einen Mixed-Methods-Ansatz: 1) Induktive-qualitative Studie auf Basis der Grounded Theory a. Ziel: Identifikation von Wirkkomponenten und deren Zusammenspiel und Generierung eines Modells b. Methoden: Verdeckte Beobachtung und narrative Interviews c. Ergebnisse: Modelle der Genese punktueller Erlebnisse und prägender Erlebnisse 2) Deduktive-quantitative Studie a. Ziel: Überprüfung und Konkretisierung der in 1) generierten Modelle b. Methoden: Fragebogengestützte, quantitative Befragung und Auswertung mittels multivariater Verfahren c. Ergebnisse: Zusammenfassung der beiden Modelle zu einem finalen Modell der Erlebnis- und Erfahrungsgenese Das Ergebnis des Vorgehens ist ein empirisch erarbeitetes und validiertes, detailliertes Modell der Genese von Erlebnissen und der Bewertung dieser durch den Erlebenden in Bezug auf deren Fähigkeit zu Erfahrungen zu werden. Neben der Aufarbeitung und Konkretisierung dieses Prozesses konnte zusätzlich die in viele Richtungen diskutierte Bedeutung von Erwartungen und Produktzufriedenheit mit Blick auf die Bewertung von Erlebnissen geklärt werden. So konnte empirisch nachgewiesen werden, dass Erlebnisse, die auf Überraschungen, dem Unerwarteten, basierten besonders resistent gegenüber Störfaktoren waren und positive Erlebnisse zwar durchaus im Zusammenhang mit Produktzufriedenheit stehen aber sich vor allem durch eine zumindest temporär gesteigerte Lebenszufriedenheit manifestieren. Damit konnte das Hauptkriterium für die Bewertung von Erlebnissen mit Blick auf ihre Tauglichkeit zu Erfahrungen identifiziert werden. Für die weitere Forschung kann die vorliegende Arbeit mit dem finalen Modell der Erlebnis- und Erfahrungsgenese einen soliden Ausgangspunkt bilden. So bieten zahlreiche Faktoren im Modell die Möglichkeit zur weiteren Forschung. Auch sollten die Ergebnisse in weiteren touristischen Kontexten überprüft werden. Für die touristische Praxis kann die vorliegende Arbeit zahlreiche Hinweise geben. So bedeutet die Generierung von Erlebnissen im touristischen Kontext mehr als nur die Erfüllung von Erwartungen. Die widerstandsfähigsten Erlebnisse sind jene, die den Gast zu überraschen vermögen. Ein qualitativ hochwertiges, den Gast zufriedenstellendes Produkt ist dabei nicht mehr als ein Basisfaktor. Wirklich erfolgreich ist ein erlebnisbasierender Ansatz nur dann, wenn dieser es vermag die Lebenszufriedenheit des Gastes zu steigern.