This thesis consists of four highly related chapters examining China’s rise in the aluminium industry. The first chapter addresses the conditions that allowed China, which first entered the market in the 1950s, to rise to world leadership in aluminium production. Although China was a latecomer, its re-entry into the market after the oil crises in the 1970s was a success and led to its ascent as the world’s largest aluminium producer by 2001. With an estimated production of 40.4 million tonnes in 2022, China represented almost 60% of the global output. Chapter 1 examines the factors underlying this success, such as the decline of international aluminium cartels, the introduction of innovative technology, the US granting China the MFN tariff status, Chinese-specific factors, and supportive government policies. Chapter 2 develops a mathematical model to analyze firms’ decisions in the short term. It examines how an incumbent with outdated technology and a new entrant with access to a new type of technology make strategic decisions, including the incumbent’s decision whether to deter entry, the production choice of firms, the optimal technology adoption rate of the newcomer, and cartel formation. Chapter 3 focuses on the adoption of new technology by firms upon market entry in four scenarios: firstly, a free market Cournot competition; secondly, a situation in which the government determines technology adoption rates; thirdly, a scenario in which the government controls both technology and production; and finally, a scenario where the government dictates technology adoption rates, production levels, and also the number of market participants. Chapter 4 applies the Spencer and Brander (1983) framework to examine strategic industrial policy. The model assumes that there are two exporting firms in two different countries that sell a product to a third country. We examine how the domestic firm is influenced by government intervention, such as the provision of a fixed-cost subsidy to improve its competitiveness relative to the foreign company. Chapter 4 initially investigates a scenario where only one government offers a fixed-cost subsidy, followed by an analysis of the case when both governments simultaneously provide financial help. Taken together, these chapters provide a comprehensive analysis of the strategic, technological, and political factors contributing to China’s leadership in the global aluminium industry. Chapter 1: The Rise of China as a Latecomer in the Global Aluminium Industry This chapter examines China’s remarkable transformation into a global leader in the aluminium industry, a sector in which the country accounted for approximately 58.9% of worldwide production in 2022. We examine how China, a latecomer to the aluminium industry that started off with labor-intensive technology in 1953, grew into the largest aluminium producer with some of the most advanced smelters in the world. This analysis identifies and discusses several opportunities that Chinese aluminium producers took advantage of. The first set of opportunities happened during the 1970s oil crises, which softened international competition and allowed China to acquire innovative smelting technology from Japan. The second set of opportunities started at about the same time when China opened its economy in 1978. The substantial demand for aluminium in China is influenced by both external and internal factors. Externally, the US granted China’s MFN tariff status in 1980 and China entered the World Trade Organization (WTO) in 2001. Both events contributed to a surge in Chinese aluminium consumption. Internally, China’s investment-led growth model boosted further its aluminium demand. Additional factors specific to China, such as low labor costs and the abundance of coal as an energy source, offer Chinese firms competitive advantages against international players. Furthermore, another window of opportunity is due to Chinese governmental policies, including phasing out old technology, providing subsidies, and gradually opening the economy to enhance domestic competition before expanding globally. By describing these elements, the study provides insights into the dynamic interplay of external circumstances and internal strategies that contributed to the success of the Chinese aluminium industry. Chapter 2: Technological Change and Strategic Choices for Incumbent and New Entrant This chapter introduces an oligopoly model that includes two actors: an incumbent and a potential entrant, that compete in the same market. We assume that two participants are located in different parts of the market: the incumbent is situated in area 1, whereas the potential entrant may venture into the other region, area 2. The incumbent exists in stage zero, where it can decide whether to deter the newcomer’s entry. A new type of technology exists in period one, when the newcomer may enter the market. In the short term, the incumbent is trapped with the outdated technology, while the new entrant may choose to partially or completely adopt the latest technology. Our results suggest the following: Firstly, the incumbent only tries to deter the new entrant if a condition for entry cost is met. Secondly, the new entrant is only interested in forming a cartel with the incumbent if a function of the ratio of the variable to new technology’s fixed-cost parameters is sufficiently high. Thirdly, if the newcomer asks to form a cartel, the incumbent will always accept this request. Finally, we can obtain the optimal new technology adoption rate for the newcomer. Chapter 3: Technological Adoption and Welfare in Cournot Oligopoly This study examines the difference between the optimal technology adoption rates chosen by firms in a homogeneous Cournot oligopoly and that preferred by a benevolent government upon firms’ market entry. To address the question of whether the technology choices of firms and government are similar, we analyze several different scenarios, which differ in the extent of government intervention in the market. Our results suggest a relationship between the number of firms in the market and the impact of government intervention on technology adoption rates. Especially in situations with a low number of firms that are interested in entering the market, greater government influence tends to lead to higher technology adoption rates of firms. Conversely, in scenarios with a higher number of firms and a government that lacks control over the number of market players, the technology adoption rate of firms will be highest when the government plays no role. Chapter 4: International Technological Innovation and Industrial Strategies Supporting domestic firms when they first enter the market may be seen as a favorable policy choice by governments around the world thanks to their ability to enhance the competitive advantage of domestic firms in non-cooperative competition against foreign enterprises (infant industry protection argument). This advantage may allow domestic firms to increase their market share and generate higher profits, thereby improving domestic welfare. This chapter utilizes the Spencer and Brander (1983) framework as a theoretical foundation to elucidate the effects of fixed-cost subsidies on firms’ production levels, technological innovations, and social welfare. The analysis examines two firms in different countries, each producing a homogeneous product that is sold in a third, separate country. We first examine the Cournot-Nash equilibrium in the absence of government intervention, followed by analyzing a scenario where just one government provides a financial subsidy for its domestic firm, and finally, we consider a situation where both governments simultaneously provide financial assistance for their respective firms. Our results suggest that governments aim to maximize social welfare by providing fixed-cost subsidies to their respective firms, finding themselves in a Chicken game scenario. Regarding technology innovation, subsidies lead to an increased technological adoption rate for recipient firms, regardless of whether one or both firms in a market receive support, compared to the situation without subsidies. The technology adoption rate of the recipient firm is higher than of its rival when only the recipient firm benefits from the fixed-cost subsidy. The lowest technology adoption rate of a firm occurs when the firm does not receive a fixed-cost subsidy, but its competitor does. Furthermore, global welfare will benefit the most in case when both exporting countries grant fixed-cost subsidies, and this welfare level is higher when only one country subsidizes than when no subsidies are provided by any country.

Introduction: This study examined the sources and factors of resilience in Russian sexual and gender minorities. We hypothesized that, through their involvement in the lesbian, gay, bisexual, and transgender (LGBT) community (source of resilience), LGBT people establish friendships that provide them with social support (factor of resilience), which in turn should contribute to their mental health. Method: The study sample consisted of 1,127 young and middle-aged LGBT adults (18 to 50 years) from Russia. We collected the data online and anonymously. Results: Partial mediation could be confirmed. LGBT people who were involved in “their” community reported more social support from friends, which partially mediated the positive association between community involvement and mental health. The mediation remained significant when we controlled for demographics and outness as potential covariates. Additional analyses showed that the present sample reported lower mental health but not less social support than Russian nonminority samples recruited in previous research. Conclusion: Our study underlines the importance of the LGBT community in times of increasing stigmatization of sexual and gender minorities.

Differential equations yield solutions that necessarily contain a certain amount of regularity and are based on local interactions. There are various natural phenomena that are not well described by local models. An important class of models that describe long-range interactions are the so-called nonlocal models, which are the subject of this work. The nonlocal operators considered here are integral operators with a finite range of interaction and the resulting models can be applied to anomalous diffusion, mechanics and multiscale problems. While the range of applications is vast, the applicability of nonlocal models can face problems such as the high computational and algorithmic complexity of fundamental tasks. One of them is the assembly of finite element discretizations of truncated, nonlocal operators. The first contribution of this thesis is therefore an openly accessible, documented Python code which allows to compute finite element approximations for nonlocal convection-diffusion problems with truncated interaction horizon. Another difficulty in the solution of nonlocal problems is that the discrete systems may be ill-conditioned which complicates the application of iterative solvers. Thus, the second contribution of this work is the construction and study of a domain decomposition type solver that is inspired by substructuring methods for differential equations. The numerical results are based on the abstract framework of nonlocal subdivisions which is introduced here and which can serve as a guideline for general nonlocal domain decomposition methods.

Der zentrale Gegenstand der Untersuchung ist die Rechtsfigur des Indigenats im Kontext der württembergischen und preußischen Staatenlandschaft. Das Indigenat lässt sich als ein Recht bestimmen, das seine potenziellen Rechtsträger maßgeblich über das Abstammungsprinzip definiert und ein Verhältnis zwischen Rechtsträger und einem übergeordneten Rechtssubjekt zum Ausdruck bringt, sei es lehns- oder standes-, staats- oder auch bundes- beziehungsweise reichsrechtlicher Natur. Der zeitliche Schwerpunkt der Betrachtung liegt auf dem 19. Jahrhundert. Es werden jedoch auch Rückblicke in die Frühe Neuzeit geworfen, weil Wandel und Kontinuität in der Entwicklung des Indigenats in einer solch langen Perspektive besonders klar hervortreten können. Die zentrale These dieser Arbeit ist, dass ein enger Zusammenhang zwischen der im 19. Jahrhundert entstehenden und bis heute geläufigen Form der Zuordnung von Menschen zum Staat und den aus diesem Verhältnis entspringenden Rechten einerseits und dem frühneuzeitlichen Indigenat andererseits besteht. Dabei kann gezeigt werden, dass Gesellschaften ihre politischen Machtpositionen gegenüber „fremdstämmigen“, etwa zuwandernden Personen abschirmten, indem sie sich auf indigenatrechtliche, ethnische Bestimmungen beriefen.

In the present study, we tested whether processing information in the context of an ancestral survival scenario enhances episodic memory performance in older adults and in stroke patients. In an online study (Experiment 1), healthy young and older adults rated words according to their relevance to an ancestral survival scenario, and subsequent free recall performance was compared to a pleasantness judgment task and a moving scenario task in a within-subject design. The typical survival processing effect was replicated: Recall rates were highest in the survival task, followed by the moving and the pleasantness judgment task. Although older adults showed overall lower recall rates, there was no evidence for differences between the age groups in the condition effects. Experiment 2 was conducted in a neurological rehabilitation clinic with a sample of patients who had suffered from a stroke within the past 5 months. On the group level, Experiment 2 revealed no significant difference in recall rates between the three conditions. However, when accounting for overall memory abilities and executive function, independently measured in standardized neuropsychological tests, patients showed a significant survival processing effect. Furthermore, only patients with high executive function scores benefitted from the scenario tasks, suggesting that intact executive function may be necessary for a mnemonic benefit. Taken together, our results support the idea that the survival processing task – a well-studied task in the field of experimental psychology – may be incorporated into a strategy to compensate for memory dysfunction.

Wie gestaltet sich die politische Kultur in Rheinland-Pfalz aus? Vor dem Hintergrund verschiedener Prägungen der Bundesländer in Deutschland nimmt das Monitoring eine spezielle Vermessung der in Rheinland-Pfalz verbreiteten politischen Einstellungen und Haltungen vor.

　

Introduction: Across various cultural contexts, success in goal realization relates to individuals’ well-being. Moreover, commitment to and successful pursuance of goals are crucial when searching for a meaningful identity in adolescence. However, individuals’ goals differ in how much they match their implicit motive dispositions. We hypothesized that successful pursuance of affiliation goals positively relates to commitment-related dimensions of interpersonal identity development (domain: close friends) that, in turn, predict adolescents’ level of well-being. However, we further assumed that the links between goal success and identity commitment are particularly pronounced among adolescents who are characterized by a high implicit affiliation motive. Methods: To scrutinize the generalizability of the assumed relationships, data were assessed among adolescents in individualistic (Germany) and collectivistic (Zambia) cultural contexts. Results: Regardless of adolescents’ cultural background, we found that commitment-related dimensions of interpersonal identity development mediate the link between successful attainment of affiliation goals and well-being, particularly among adolescents with a pronounced implicit affiliation motive; that is, the strength of the implicit affiliation motive moderates the association between goal success and identity commitment. Conclusion: We discuss findings concerning universal effects of implicit motives on identity commitment and well-being.

　

This article investigates selected texts and oral performances by two contemporary authors, Nico Bleutge and Mette Moestrup, who adapt or rewrite Christensen’s poems. In the works focused on (Moestrups poems “My Language” and “Hvad betyder det for sommerfuglen”, Bleutge’s speech “Den Wiederholungen folgen” and the poem “fischhaare finden”), translation plays a central role, and animals (especially winged ones) become a motor for transformational movements between languages and authors. Unsettling the semantic and structural level of language, the named birds and butterflies set loose acoustic dynamics that lead us back to Christensen’s reflections on mortality, contingency, and poetics in her essays.

When humans encounter attitude objects (e.g., other people, objects, or constructs), they evaluate them. Often, these evaluations are based on attitudes. Whereas most research focuses on univalent (i.e., only positive or only negative) attitude formation, little research exists on ambivalent (i.e., simultaneously positive and negative) attitude formation. Following a general introduction into ambivalence, I present three original manuscripts investigating ambivalent attitude formation. The first manuscript addresses ambivalent attitude formation from previously univalent attitudes. The results indicate that responding to a univalent attitude object incongruently leads to ambivalence measured via mouse tracking but not ambivalence measured via self-report. The second manuscript addresses whether the same number of positive and negative statements presented block-wise in an impression formation task leads to ambivalence. The third manuscript also used an impression formation task and addresses the question of whether randomly presenting the same number of positive and negative statements leads to ambivalence. Additionally, the effect of block size of the same valent statements is investigated. The results of the last two manuscripts indicate that presenting all statements of one valence and then all statements of the opposite valence leads to ambivalence measured via self-report and mouse tracking. Finally, I discuss implications for attitude theory and research as well as future research directions.

The article considers the circulation and the role of the motifs China, the Chinese man/woman and the Chinese as concepts of the other/strange(r), which negatively correspond to the concepts of the self in the work of the Russian poet, writer, artist and producer of performances Dmitrij Prigov. These phenomena and their historical development are of special interest in the present context of the Russian war against Ukraine, the Western sanctions against Russia and the growing political, economic and military approximation of Russia to China. In its analytic design the article discerns in Prigov’s China-text a broader geo-esthetical from a smaller geo-poetical horizon and distinguishes the theme- and sense-orientated phenomenon of stereotype, reducing (the concept of) a culture or a nation to special, often discrediting it, semantic features (as topoi), from the phenomenon of the imagotype, which is orientated to the poetical and/or esthetical construction of an artifact and relates the specialty of the other to certain sounds, intonations, colors, textures. Reconstructing the development of the motifs of China, the Chinese man/woman and the Chinese in Prigov’s China-text from the 1970s up to the posthumously in 2013 published novel “Katia, the Chinese”, the article shows that the evolution of the imagotypes and stereotypes of China, the Chinese man / woman and the Chinese as concepts of the other/alien is correlated with the development of the geopolitical relation of Russia and China.

Job crafting is the behavior that employees engage in to create personally better fitting work environments, for example, by increasing challenging job demands. To better understand the driving forces behind employees’ engagement in job crafting, we investigated implicit and explicit power motives. While implicit motives tend to operate at the unconscious, explicit motives operate at the unconscious level. We focused on power motives, as power is an agentic motive characterized by the need to influence your environment. Although power is relevant to job crafting in its entirety, in this study, we link it to increasing challenging job demands due to its relevance to job control, which falls under the umbrella of power. Using a cross-sectional design, we collected survey data from a sample of Lebanese nurses (N = 360) working in 18 different hospitals across the country. In both implicit and explicit power motive measures, we focused on integrative power that enable people to stay calm and integrate opposition. The results showed that explicit power predicted job crafting (H1) and that implicit power amplified this effect (H2). Furthermore, job crafting mediated the relationship between congruently high power motives and positive work-related outcomes (H3) that were interrelated (H4). Our findings unravel the driving forces behind one of the most important dimensions of job crafting and extend the benefits of motive congruence to work-related outcomes.

　

Introduction: Conventional agricultural land-use may negatively impact biodiversity and the environment due to the increased disturbances to the soil ecosystem by tillage, for example. Cultivation of the perennial grain intermediate wheatgrass (Thinopyrum intermedium, IWG, Kernza®) is a nature-based solution for sustainable agriculture, improving nutrient retention mainly through its extensive root system. Nematodes serve as sensitive bioindicators, detecting early changes in the soil food web, reflecting in changes in their community structure. Materials and Methods:IWG and annual wheat sites in South France, Belgium and South Sweden were investigated in April 2022 for two depths (5–15 cm; 25–35 cm) to evaluate the difference in nematode community structure among the cropping systems. Results: Sites with IWG cultivation held an accumulation of structure indicators (c-p 3–5 nematodes) compared to sites with annual wheat cultivation. A generalised linear mixed model revealed significantly more root feeders, especially for the subsoil, under IWG as a result of the perennial cultivation. The maturity index, plant-parasitic index, channel index and structure index were greater for IWG sites. The enrichment index was greater for annual wheat sites due to the dominance of bacterivores and enrichment indicators (c-p 1 nematodes). The nematode community structure (weighted faunal profile analysis) indicates IWG sites as being a generally undisturbed system with efficient nutrient cycling and balanced distribution of feeding types, as well as higher metabolic footprint values for root feeders (including plant-parasitic nematodes) and fungivores. Annual wheat sites, on the other hand, held indicators of a disturbed system with increased occurrence of opportunistic species and a more bacterial driven pathway. The topsoil had an increased occurrence of structure indicators in both cropping systems. Conclusion: IWG creates favourable conditions for a diverse food web, including improved nutrient cycling and a heterogeneous resource environment, regardless of climatic conditions, establishing it as a stable and resilient agricultural management system.

In the face of uncontrollable complexity, the concept of a rational design of the organization is being replaced by the notion of an open future that is inherently unpredictable and unplanable. In rapidly changing environments, organizations and leaders are confronted with a constant stream of irritations and unexpected developments, that require ongoing attention. This prompts the question of whether the conceptualization of digital transformation as a paradigm shift also implies the need for new forms of leadership. The article analyzes the discourse on digital leadership and assesses the extent to which this concept relativizes leadership in the context of the evolution of leadership theory, which is characterized by a persistent process of modification and relativization of preceding concepts. Leadership concepts are not only responsive to general needs, but also vary according to specific contexts, such as non-profit leadership or leadership in social welfare organizations and meta-organizations. Results of a discourse analysis, which underscore the significance of adopting a complexity theory perspective on digital leadership, will therefore be contrasted with the initial findings of an empirical study on digitization in such meta-organizations. This allows for a discussion of the general findings on the revitalization of leadership, which will serve as a paradigmatic example of the previously developed context. The article concludes with implications for further theory development with the aim of making a specific contribution to organization-sensitive digitization research. The findings of the empirical study indicate the significance of employing informal structures and a heightened emphasis on subjectivity within meta-organizations, as opposed to the formal structures of organizations. The concept of digital leadership does not signify the obsolescence of traditional leadership; rather, it can be conceptualized as an advanced form of unheroic leadership within the context of external and internal complexity.

Income is one of the key indicators to measure regional differences, individual opportunities, and inequalities in society. In Germany, the regional distribution of income is a central concern, especially regarding persistent East-West, North-South, or urban-rural inequalities. Effective local policies and institutions require reliable data and indicators on regional inequality. However, its measurement faces severe data limitations: Inconsistencies in the existing microdata sources yield an inconclusive picture of regional inequality. While survey data provide a wide range of individual and household information but lack top incomes, tax data contain the most reliable income records but offer a limited range of socio-demographic variables essential for income analysis. In addition, information on the long-term evolution of the income distribution at the small-scale level is scarce. In this context, this thesis evaluates regional income inequality in Germany from various perspectives and embeds three self-contained studies in Chapters 3, 4, and 5, which present different data integration approaches. The first chapter motivates this thesis, while the second chapter provides a brief overview of the theoretical and empirical concepts as well as the datasets, highlighting the need to combine data from different sources. Chapter 3 tackles the issue of poor coverage of top incomes in surveys, also referred to as the ’missing rich’ problem, which leads to severe underestimation of income inequality. At the regional level this shortcoming is even more eminent due to small regional sample sizes. Based on reconciled tax and survey data, this chapter therefore proposes a new multiple imputation top income correction approach that, unlike previous research, focuses on the regional rather than the national level. The findings indicate that inequality between and within the regions is much larger than previously understood with the magnitude of the adjustment depending on the federal states’ level of inequality in the tail. To increase the potential of the tax data for income analysis and to overcome the lack of socio-demographic characteristics, Chapter 4 enriches the tax data with information on education and working time from survey data. For that purpose, a simulation study evaluates missing data methods and performant prediction models, finding that Multinomial Regression and Random Forest are the most suitable methods for the specific data fusion scenario. The results indicate that data fusion approaches broaden the scope for regional inequality analysis from cross-sectional enhanced tax data. Shifting from a cross-sectional to a longitudinal perspective on regional income inequality, Chapter 5 contributes to the currently relatively small body of literature dealing with the potential development of regional income disparities over time. Regionalized dynamic microsimulations provide a powerful tool for the study of long-term income developments. Therefore, this chapter extends the microsimulation model MikroSim with an income module that accounts for the individual, household, and regional context. On this basis, the potential dynamics in gender and migrant income gaps across the districts in Germany are simulated under scenarios of increased full-time employment rates and higher levels of tertiary education. The results show that the scenarios have regionally differing effects on inequality dynamics, highlighting the considerable potential of dynamic microsimulations for regional evidence-based policies. For the German case, the MikroSim model is well suited to analyze future regional developments and can be flexibly adapted for further specific research questions.

The cold pressor test (CPT) elicits strong cardiovascular reactions via activation of the sympathetic nervous system (SNS), yielding subsequent increases in heart rate (HR) and blood pressure (BP). However, little is known on how exposure to the CPT affects cardiac ventricular repolarization. Twenty-eight healthy males underwent both a bilateral feet CPT and a warm water (WW) control condition on two separate days, one week apart. During pre-stress baseline and stress induction cardiovascular signals (ECG lead II, Finometer BP) were monitored continuously. Salivary cortisol and subjective stress ratings were assessed intermittently. Corrected QT (QTc) interval length and T-wave amplitude (TWA) were assessed for each heartbeat and subsequently aggregated individually over baseline and stress phases, respectively. CPT increases QTc interval length and elevates the TWA. Stress-induced changes in cardiac repolarization are only in part and weakly correlated with cardiovascular and cortisol stress-reactivity. Besides its already well-established effects on cardiovascular, endocrine, and subjective responses, CPT also impacts on cardiac repolarization by elongation of QTc interval length and elevation of TWA. CPT effects on cardiac repolarization share little variance with the other indices of stress reactivity, suggesting a potentially incremental value of this parameter for understanding psychobiological adaptation to acute CPT stress.

　

　

Knowledge acquisition comprises various processes. Each of those has its dedicated research domain. Two examples are the relations between knowledge types and the influences of person-related variables. Furthermore, the transfer of knowledge is another crucial domain in educational research. I investigated these three processes through secondary analyses in this dissertation. Secondary analyses comply with the broadness of each field and yield the possibility of more general interpretations. The dissertation includes three meta-analyses: The first meta-analysis reports findings on the predictive relations between conceptual and procedural knowledge in mathematics in a cross-lagged panel model. The second meta-analysis focuses on the mediating effects of motivational constructs on the relationship between prior knowledge and knowledge after learning. The third meta-analysis deals with the effect of instructional methods in transfer interventions on knowledge transfer in school students. These three studies provide insights into the determinants and processes of knowledge acquisition and transfer. Knowledge types are interrelated; motivation mediates the relation between prior and later knowledge, and interventions influence knowledge transfer. The results are discussed by examining six key insights that build upon the three studies. Additionally, practical implications, as well as methodological and content-related ideas for further research, are provided.

Un débat politique passionnant a lieu en classe. La plupart de vos élèves sont attentif·ve·s, intéressé·e·s et engagé·e·s. Tout se passe à merveille, jusqu’à ce qu’un·e élève lance – délibérément ou sans réfléchir – des propos extrémistes ou complotistes. Comment réagir ?

　

Sowohl national als auch international wird die zunehmende Digitalisierung von Prozessen gefordert. Die Heterogenität und Komplexität der dabei entstehenden Systeme erschwert die Partizipation für reguläre Nutzergruppen, welche zum Beispiel kein Expertenwissen in der Programmierung oder einen informationstechnischen Hintergrund aufweisen. Als Beispiel seien hier Smart Contracts genannt, deren Programmierung komplex ist und bei denen etwaige Fehler unmittelbar mit monetärem Verlust durch die direkte Verknüpfung der darunterliegenden Kryptowährung verbunden sind. Die vorliegende Arbeit stellt ein alternatives Protokoll für cyber-physische Verträge vor, das sich besonders gut für die menschliche Interaktion eignet und auch von regulären Nutzergruppen verstanden werden kann. Hierbei liegt der Fokus auf der Transparenz der Übereinkünfte und es wird weder eine Blockchain noch eine darauf beruhende digitale Währung verwendet. Entsprechend kann das Vertragsmodell der Arbeit als nachvollziehbare Verknüpfung zwischen zwei Parteien verstanden werden, welches die unterschiedlichen Systeme sicher miteinander verbindet und so die Selbstorganisation fördert. Diese Verbindung kann entweder computergestützt automatisch ablaufen, oder auch manuell durchgeführt werden. Im Gegensatz zu Smart Contracts können somit Prozesse Stück für Stück digitalisiert werden. Die Übereinkünfte selbst können zur Kommunikation, aber auch für rechtlich bindende Verträge genutzt werden. Die Arbeit ordnet das neue Konzept in verwandte Strömungen wie Ricardian oder Smart Contracts ein und definiert Ziele für das Protokoll, welche in Form der Referenzimplementierung umgesetzt werden. Sowohl das Protokoll als auch die Implementierung werden im Detail beschrieben und durch eine Erweiterung der Anwendung ergänzt, welche es Nutzenden in Regionen ohne direkte Internetverbindung ermöglicht, an ebenjenen Verträgen teilnehmen zu können. Weiterhin betrachtet die Evaluation die rechtlichen Rahmenbedinungen, die Übertragung des Protokolls auf Smart Contracts und die Performanz der Implementierung.

The cumulative and bidirectional groundwater-surface water (GW-SW) interaction along a stream is defined as hydrological turnover (HT) influencing solute transport and source water composition. However, HT proves to be highly variable, producing spatial exchange patterns influenced by local groundwater, geology, and topography. Hence, identifying factors controlling HT poses a challenge. We studied spatiotemporal HT variability at two reaches of a third order tributary of the river Mosel, Germany. Additionally, we sampled for silica concentrations in the stream and in the near-stream groundwater. Thus, creating snapshots of the boundary layer between ground- and surface water where HT occurs, driven by mixing processes in the hyporheic zone. We utilize an enhanced hydrograph separation method, unveiling reach differences in storage drainage based on aquifer dimension and connectivity. The data shows a site-specific negative correlation of HT with discharge, while hydraulic gradients correlate with HT only at the reach with faster catchment drainage behavior. Examining silica concentrations between stream and wells shows that silica variation increases significantly with the decrease of HT under low flow conditions at the slower draining reach. At the fast draining reach this relationship is seasonal. In Summary, our results show that stream discharge shapes the influence of HT on solute transport. Yet, reach drainage behavior shapes seasonal states of groundwater storages and can be an additional control of HT. Hence, concentration change of pollutants could be masked by HT. Thus, our findings contribute to the understanding of HT variability along streams and its ability of influencing physico-chemical stream water composition.