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Physically-based distributed rainfall-runoff models as the standard analysis tools for hydro-logical processes have been used to simulate the water system in detail, which includes spa-tial patterns and temporal dynamics of hydrological variables and processes (Davison et al., 2015; Ek and Holtslag, 2004). In general, catchment models are parameterized with spatial information on soil, vegetation and topography. However, traditional approaches for eval-uation of the hydrological model performance are usually motivated with respect to dis-charge data alone. This may thus cloud model realism and hamper understanding of the catchment behavior. It is necessary to evaluate the model performance with respect to in-ternal hydrological processes within the catchment area as well as other components of wa-ter balance rather than runoff discharge at the catchment outlet only. In particular, a consid-erable amount of dynamics in a catchment occurs in the processes related to interactions of the water, soil and vegetation. Evapotranspiration process, for instance, is one of those key interactive elements, and the parameterization of soil and vegetation in water balance mod-eling strongly influences the simulation of evapotranspiration. Specifically, to parameterize the water flow in unsaturated soil zone, the functional relationships that describe the soil water retention and hydraulic conductivity characteristics are important. To define these functional relationships, Pedo-Transfer Functions (PTFs) are common to use in hydrologi-cal modeling. Opting the appropriate PTFs for the region under investigation is a crucial task in estimating the soil hydraulic parameters, but this choice in a hydrological model is often made arbitrary and without evaluating the spatial and temporal patterns of evapotran-spiration, soil moisture, and distribution and intensity of runoff processes. This may ulti-mately lead to implausible modeling results and possibly to incorrect decisions in regional water management. Therefore, the use of reliable evaluation approaches is continually re-quired to analyze the dynamics of the current interactive hydrological processes and predict the future changes in the water cycle, which eventually contributes to sustainable environ-mental planning and decisions in water management.
Remarkable endeavors have been made in development of modelling tools that provide insights into the current and future of hydrological patterns in different scales and their im-pacts on the water resources and climate changes (Doell et al., 2014; Wood et al., 2011). Although, there is a need to consider a proper balance between parameter identifiability and the model's ability to realistically represent the response of the natural system. Neverthe-less, tackling this issue entails investigation of additional information, which usually has to be elaborately assembled, for instance, by mapping the dominant runoff generation pro-cesses in the intended area, or retrieving the spatial patterns of soil moisture and evapotran-spiration by using remote sensing methods, and evaluation at a scale commensurate with hydrological model (Koch et al., 2022; Zink et al., 2018). The present work therefore aims to give insights into the modeling approaches to simulate water balance and to improve the soil and vegetation parameterization scheme in the hydrological model subject to producing more reliable spatial and temporal patterns of evapotranspiration and runoff processes in the catchment.
An important contribution to the overall body of work is a book chapter included among publications. The book chapter provides a comprehensive overview of the topic and valua-ble insights into the understanding the water balance and its estimation methods.
Moreover, the first paper aimed to evaluate the hydrological model behavior with re-spect to contribution of various sources of information. To do so, a multi-criteria evaluation metric including soft and hard data was used to define constraints on outputs of the 1-D hydrological model WaSiM-ETH. Applying this evaluation metric, we could identify the optimal soil and vegetation parameter sets that resulted in a “behavioral” forest stand water balance model. It was found out that even if simulations of transpiration and soil water con-tent are consistent with measured data, but still the dominant runoff generation processes or total water balance might be wrongly calculated. Therefore, only using an evaluation scheme which looks over different sources of data and embraces an understanding of the local controls of water loss through soil and plant, allowed us to exclude the unrealistic modeling outputs. The results suggested that we may need to question the generally accept-ed soil parameterization procedures that apply default parameter sets.
The second paper attempts to tackle the pointed model evaluation hindrance by getting down to the small-scale catchment (in Bavaria). Here, a methodology was introduced to analyze the sensitivity of the catchment water balance model to the choice of the Pedo-Transfer Functions (PTF). By varying the underlying PTFs in a calibrated and validated model, we could determine the resulting effects on the spatial distribution of soil hydraulic properties, total water balance in catchment outlet, and the spatial and temporal variation of the runoff components. Results revealed that the water distribution in the hydrologic system significantly differs amongst various PTFs. Moreover, the simulations of water balance components showed high sensitivity to the spatial distribution of soil hydraulic properties. Therefore, it was suggested that opting the PTFs in hydrological modeling should be care-fully tested by looking over the spatio-temporal distribution of simulated evapotranspira-tion and runoff generation processes, whether they are reasonably represented.
To fulfill the previous studies’ suggestions, the third paper then aims to focus on evalu-ating the hydrological model through improving the spatial representation of dominant run-off processes. It was implemented in a mesoscale catchment in southwestern Germany us-ing the hydrological model WaSiM-ETH. Dealing with the issues of inadequate spatial ob-servations for rigorous spatial model evaluation, we made use of a reference soil hydrologic map available for the study area to discern the expected dominant runoff processes across a wide range of hydrological conditions. The model was parameterized by applying 11 PTFs and run by multiple synthetic rainfall events. To compare the simulated spatial patterns to the patterns derived by digital soil map, a multiple-component spatial performance metric (SPAEF) was applied. The simulated DRPs showed a large variability with regard to land use, topography, applied rainfall rates, and the different PTFs, which highly influence the rapid runoff generation under wet conditions.
The three published manuscripts proceeded towards the model evaluation viewpoints that ultimately attain the behavioral model outputs. It was performed through obtaining information about internal hydrological processes that lead to certain model behaviors, and also about the function and sensitivity of some of the soil and vegetation parameters that may primarily influence those internal processes in a catchment. Accordingly, using this understanding on model reactions, and by setting multiple evaluation criteria, it was possi-ble to identify which parameterization could lead to behavioral model realization. This work, in fact, will contribute to solving some of the issues (e.g., spatial variability and modeling methods) identified as the 23 unsolved problems in hydrology in the 21st century (Blöschl et al., 2019). The results obtained in the present work encourage the further inves-tigations toward a comprehensive model calibration procedure considering multiple data sources simultaneously. This will enable developing the new perspectives to the current parameter estimation methods, which in essence, focus on reproducing the plausible dy-namics (spatio-temporal) of the other hydrological processes within the watershed.
Wasserbezogene regulierende und versorgende Ökosystemdienstleistungen (ÖSDL) wurden im Hinblick auf das Abflussregime und die Grundwasserneubildung im Biosphärenreservat Pfälzerwald im Südwesten Deutschlands anhand hydrologischer Modellierung unter Verwendung des Soil and Water Assessment Tool (SWAT+) untersucht. Dabei wurde ein holistischer Ansatz verfolgt, wonach den ÖSDL Indikatoren für funktionale und strukturelle ökologische Prozesse zugeordnet werden. Potenzielle Risikofaktoren für die Verschlechterung von wasserbedingten ÖSDL des Waldes, wie Bodenverdichtung durch Befahren mit schweren Maschinen im Zuge von Holzerntearbeiten, Schadflächen mit Verjüngung, entweder durch waldbauliche Bewirtschaftungspraktiken oder durch Windwurf, Schädlinge und Kalamitäten im Zuge des Klimawandels, sowie der Kli-mawandel selbst als wesentlicher Stressor für Waldökosysteme wurden hinsichtlich ihrer Auswirkungen auf hydrologische Prozesse analysiert. Für jeden dieser Einflussfaktoren wurden separate SWAT+-Modellszenarien erstellt und mit dem kalibrierten Basismodell verglichen, das die aktuellen Wassereinzugsgebietsbedingungen basierend auf Felddaten repräsentierte. Die Simulationen bestätigten günstige Bedingungen für die Grundwasserneubildung im Pfälzerwald. Im Zusammenhang mit der hohen Versickerungskapazität der Bodensubstrate der Buntsandsteinverwitterung, sowie dem verzögernden und puffernden Einfluss der Baumkronen auf das Niederschlagswasser, wurde eine signifikante Minderungswirkung auf die Oberflächenabflussbildung und ein ausgeprägtes räumliches und zeitliches Rückhaltepotential im Einzugsgebiet simuliert. Dabei wurde festgestellt, dass erhöhte Niederschlagsmengen, die die Versickerungskapazität der sandigen Böden übersteigen, zu einer kurz geschlossenen Abflussreaktion mit ausgeprägten Oberflächenabflussspitzen führen. Die Simulationen zeigten Wechselwirkungen zwischen Wald und Wasserkreislauf sowie die hydrologische Wirksamkeit des Klimawandels, verschlechterter Bodenfunktionen und altersbezogener Bestandesstrukturen im Zusammenhang mit Unterschieden in der Baumkronenausprägung. Zukunfts-Klimaprojektionen, die mit BIAS-bereinigten REKLIES- und EURO-CORDEX-Regionalklimamodellen (RCM) simuliert wurden, prognostizierten einen höheren Verdunstungsbedarf und eine Verlängerung der Vegetationsperiode bei gleichzeitig häufiger auftretenden Dürreperioden innerhalb der Vegetationszeit, was eine Verkürzung der Periode für die Grundwasserneubildung induzierte, und folglich zu einem prognostizierten Rückgang der Grundwasserneubildungsrate bis zur Mitte des Jahrhunderts führte. Aufgrund der starken Korrelation mit Niederschlagsintensitäten und der Dauer von Niederschlagsereignissen, bei allen Unsicherheiten in ihrer Vorhersage, wurde für die Oberflächenabflussgenese eine Steigerung bis zum Ende des Jahrhunderts prognostiziert.
Für die Simulation der Bodenverdichtung wurden die Trockenrohdichte des Bodens und die SCS Curve Number in SWAT+ gemäß Daten aus Befahrungsversuchen im Gebiet angepasst. Die günstigen Infiltrationsbedingungen und die relativ geringe Anfälligkeit für Bodenverdichtung der grobkörnigen Buntsandsteinverwitterung dominierten die hydrologischen Auswirkungen auf Wassereinzugsgebietsebene, sodass lediglich moderate Verschlechterungen wasserbezogener ÖSDL angezeigt wurden. Die Simulationen zeigten weiterhin einen deutlichen Einfluss der Bodenart auf die hydrologische Reaktion nach Bodenverdichtung auf Rückegassen und stützen damit die Annahme, dass die Anfälligkeit von Böden gegenüber Verdichtung mit dem Anteil an Schluff- und Tonbodenpartikeln zunimmt. Eine erhöhte Oberflächenabflussgenese ergab sich durch das Wegenetz im Gesamtgebiet.
Schadflächen mit Bestandesverjüngung wurden anhand eines artifiziellen Modells innerhalb eines Teileinzugsgebiets unter der Annahme von 3-jährigen Baumsetzlingen in einem Entwicklungszeitraum von 10 Jahren simuliert und hinsichtlich spezifischer Was-serhaushaltskomponenten mit Altbeständen (30 bis 80 Jahre) verglichen. Die Simulation ließ darauf schließen, dass bei fehlender Kronenüberschirmung die hydrologisch verzögernde Wirkung der Bestände beeinträchtigt wird, was die Entstehung von Oberflächenabfluss begünstigt und eine quantitativ geringfügig höhere Tiefensickerung fördert. Hydrologische Unterschiede zwischen dem geschlossenem Kronendach der Altbestände und Jungbeständen mit annähernden Freilandniederschlagsbedingungen wurden durch die dominierenden Faktoren atmosphärischer Verdunstungsanstoß, Niederschlagsmengen und Kronenüberschirmungsgrad bestimmt. Je weniger entwickelt das Kronendach von verjüngten Waldbeständen im Vergleich zu Altbeständen, je höher der atmosphärische Verdunstungsanstoß und je geringer die eingetragenen Niederschlagsmengen, desto größer war der hydrologische Unterschied zwischen den Bestandestypen.
Verbesserungsmaßnahmen für den dezentralen Hochwasserschutz sollten folglich kritische Bereiche für die Abflussbildung im Wald (CSA) berücksichtigen. Die hohe Sensibilität und Anfälligkeit der Wälder gegenüber Verschlechterungen der Ökosystembedingungen legen nahe, dass die Erhaltung des komplexen Gefüges und von intakten Wechselbeziehungen, insbesondere unter der gegebenen Herausforderung des Klimawandels, sorgfältig angepasste Schutzmaßnahmen, Anstrengungen bei der Identifizierung von CSA sowie die Erhaltung und Wiederherstellung der hydrologischen Kontinuität in Waldbeständen erfordern.
Addition of Phosphogypsum to Fire-Resistant Plaster Panels:
A Physic–Mechanical Investigation
(2023)
Gypsum (GPS) has great potential for structural fire protection and is increasingly used in construction due to its high-water retention and purity. However, many researchers aim to improve its physical and mechanical properties by adding other organic or inorganic materials such as fibers, recycled GPS, and waste residues. This study used a novel method to add non-natural GPS from factory waste (phosphogypsum (PG)) as a secondary material for GPS. This paper proposes to mix these two materials to properly study the effect of PG on the physico-mechanical properties and fire performance of two Tunisian GPSs (GPS1 and GPS2). PG initially replaced GPS at 10, 20, 30, 40, and 50% weight percentage (mixing plan A). The PGs were then washed with distilled water several times. Two more mixing plans were run when the pH of the PG was equal to 2.4 (mixing plan B), and the pH was equal to 5 (mixing plan C). Finally, a comparative study was conducted on the compressive strength, flexural strength, density, water retention, and mass loss levels after 90 days of drying, before/after incineration of samples at 15, 30, 45, and 60 min. The results show that the mixture of GPS1 and 30% PG (mixing plan B) obtained the highest compressive strength (41.31%) and flexural strength (35.03%) compared to the reference sample. The addition of 10% PG to GPS1 (mixing plan A) improved fire resistance (33.33%) and the mass loss (17.10%) of the samples exposed to flame for 60 min compared to GPS2. Therefore, PG can be considered an excellent insulating material, which can increase physico-mechanical properties and fire resistance time of plaster under certain conditions.
Properties Evaluation of Composite Materials Based on Gypsum Plaster and Posidonia Oceanica Fibers
(2023)
Estimating the amount of material without significant losses at the end of hybrid casting is a problem addressed in this study. To minimize manufacturing costs and improve the accuracy of results, a correction factor (CF) was used in the formula to estimate the volume percent of the material in order to reduce material losses during the sample manufacturing stage, allowing for greater confidence between the approved blending plan and the results obtained. In this context, three material mixing schemes of different sizes and shapes (gypsum plaster, sand (0/2), gravel (2/4), and Posidonia oceanica fibers (PO)) were created to verify the efficiency of CF and more precisely study the physico-mechanical effects on the samples. The results show that the use of a CF can reduce mixing loss to almost 0%. The optimal compressive strength of the sample (S1B) with the lowest mixing loss was 7.50 MPa. Under optimal conditions, the addition of PO improves mix volume percent correction (negligible), flexural strength (5.45%), density (18%), and porosity (3.70%) compared with S1B. On the other hand, the addition of PO thermo-chemical treatment by NaOH increases the compressive strength (3.97%) compared with PO due to the removal of impurities on the fiber surface, as shown by scanning electron microscopy. We then determined the optimal mixture ratio (PO divided by a mixture of plaster, sand, and gravel), which equals 0.0321 because Tunisian gypsum contains small amounts of bassanite and calcite, as shown by the X-ray diffraction results.
Forest inventories provide significant monitoring information on forest health, biodiversity,
resilience against disturbance, as well as its biomass and timber harvesting potential. For this
purpose, modern inventories increasingly exploit the advantages of airborne laser scanning (ALS)
and terrestrial laser scanning (TLS).
Although tree crown detection and delineation using ALS can be seen as a mature discipline, the
identification of individual stems is a rarely addressed task. In particular, the informative value of
the stem attributes—especially the inclination characteristics—is hardly known. In addition, a lack
of tools for the processing and fusion of forest-related data sources can be identified. The given
thesis addresses these research gaps in four peer-reviewed papers, while a focus is set on the
suitability of ALS data for the detection and analysis of tree stems.
In addition to providing a novel post-processing strategy for geo-referencing forest inventory plots,
the thesis could show that ALS-based stem detections are very reliable and their positions are
accurate. In particular, the stems have shown to be suited to study prevailing trunk inclination
angles and orientations, while a species-specific down-slope inclination of the tree stems and a
leeward orientation of conifers could be observed.
Agricultural monitoring is necessary. Since the beginning of the Holocene, human agricultural
practices have been shaping the face of the earth, and today around one third of the ice-free land
mass consists of cropland and pastures. While agriculture is necessary for our survival, the
intensity has caused many negative externalities, such as enormous freshwater consumption, the
loss of forests and biodiversity, greenhouse gas emissions as well as soil erosion and degradation.
Some of these externalities can potentially be ameliorated by careful allocation of crops and
cropping practices, while at the same time the state of these crops has to be monitored in order
to assess food security. Modern day satellite-based earth observation can be an adequate tool to
quantify abundance of crop types, i.e., produce spatially explicit crop type maps. The resources to
do so, in terms of input data, reference data and classification algorithms have been constantly
improving over the past 60 years, and we live now in a time where fully operational satellites
produce freely available imagery with often less than monthly revisit times at high spatial
resolution. At the same time, classification models have been constantly evolving from
distribution based statistical algorithms, over machine learning to the now ubiquitous deep
learning.
In this environment, we used an explorative approach to advance the state of the art of crop
classification. We conducted regional case studies, focused on the study region of the Eifelkreis
Bitburg-Prüm, aiming to develop validated crop classification toolchains. Because of their unique
role in the regional agricultural system and because of their specific phenologic characteristics
we focused solely on maize fields.
In the first case study, we generated reference data for the years 2009 and 2016 in the study
region by drawing polygons based on high resolution aerial imagery, and used these in
conjunction with RapidEye imagery to produce high resolution maize maps with a random forest
classifier and a gaussian blur filter. We were able to highlight the importance of careful residual
analysis, especially in terms of autocorrelation. As an end result, we were able to prove that, in
spite of the severe limitations introduced by the restricted acquisition windows due to cloud
coverage, high quality maps could be produced for two years, and the regional development of
maize cultivation could be quantified.
In the second case study, we used these spatially explicit datasets to link the expansion of biogas
producing units with the extended maize cultivation in the area. In a next step, we overlayed the
maize maps with soil and slope rasters in order to assess spatially explicit risks of soil compaction
and erosion. Thus, we were able to highlight the potential role of remote sensing-based crop type
classification in environmental protection, by producing maps of potential soil hazards, which can
be used by local stakeholders to reallocate certain crop types to locations with less associated
risk.
In our third case study, we used Sentinel-1 data as input imagery, and official statistical records
as maize reference data, and were able to produce consistent modeling input data for four
consecutive years. Using these datasets, we could train and validate different models in spatially
iv
and temporally independent random subsets, with the goal of assessing model transferability. We
were able to show that state-of-the-art deep learning models such as UNET performed
significantly superior to conventional models like random forests, if the model was validated in a
different year or a different regional subset. We highlighted and discussed the implications on
modeling robustness, and the potential usefulness of deep learning models in building fully
operational global crop classification models.
We were able to conclude that the first major barrier for global classification models is the
reference data. Since most research in this area is still conducted with local field surveys, and only
few countries have access to official agricultural records, more global cooperation is necessary to
build harmonized and regionally stratified datasets. The second major barrier is the classification
algorithm. While a lot of progress has been made in this area, the current trend of many appearing
new types of deep learning models shows great promise, but has not yet consolidated. There is
still a lot of research necessary, to determine which models perform the best and most robust,
and are at the same time transparent and usable by non-experts such that they can be applied
and used effortlessly by local and global stakeholders.
The argan woodlands of South Morocco represent an open-canopy dryland forest with traditional silvopastoral usage that includes browsing by goats, sheep and camels, oil production as well as agricultural use. In the past, these forests have undergone extensive clearing, but are now protected by the state. However, the remaining argan woodlands are still under pressure from intensive grazing and illegal firewood collection. Although the argan-forest area seems to be overall decreasing due to large forest clearings for intensive agriculture, little quantitative data is available on the dynamics and overall state of the remaining argan forest. To determine how the argan woodlands in the High Atlas and the Anti-Atlas had changed in tree-crown cover from 1972 to 2018 we used historical black and white HEXAGON satellite images as well as recent WorldView satellite images (see Part A of our study). Because tree shadows can oftentimes not be separated from the tree crown on panchromatic satellite images, individual trees were mapped in three size categories to determine if trees were unchanged, had decreased/increased in crown size or had disappeared or newly grown. The current state of the argan trees was evaluated by mapping tree architectures in the field. Tree-cover changes varied highly between the test sites. Trees that remained unchanged between 1972 and 2018 were in the majority, while tree mortality and tree establishment were nearly even. Small unchanged trees made up 48.4% of all remaining trees, of these 51% showed degraded tree architectures. 40% of small (re-) grown trees were so overbrowsed that they only appeared as bushes, while medium (3–7 m crown diameter) and large trees (>7 m) showed less degraded trees regardless if they had changed or not. Approaches like grazing exclusion or cereal cultivation lead to a positive influence on tree architecture and less tree-cover decrease. Although the woodland was found to be mostly unchanged 1972–2018, the analysis of tree architecture reveals that a lot of (mostly small) trees remained stable but in a degraded state. This stability might be the result of the small trees’ high degradation status and shows the heavy pressure on the argan forest.
Climate fluctuations and the pyroclastic depositions from volcanic activity both influence ecosystem functioning and biogeochemical cycling in terrestrial and marine environments globally. These controlling factors are crucial for the evolution and fate of the pristine but fragile fjord ecosystem in the Magellanic moorlands (~53°S) of southernmost Patagonia, which is considered a critical hotspot for organic carbon burial and marine bioproductivity. At this active continental margin in the core zone of the southern westerly wind belt (SWW), frequent Plinian eruptions and the extremely variable, hyper-humid climate should have efficiently shaped ecosystem functioning and land-to-fjord mass transfer throughout the Late Holocene. However, a better understanding of the complex process network defining the biogeochemical cycling at this land-to-fjord continuum principally requires a detailed knowledge of substrate weathering and pedogenesis in the context of the extreme climate. Yet, research on soils, the ubiquitous presence of tephra and the associated chemical weathering, secondary mineral (trans)formation and organic matter (OM) turnover processes is rare in this remote region. This complicates an accurate reconstruction of the ecosystem´s potentially sensitive response to past environmental impacts, including the dynamics of Late Holocene land-to-fjord fluxes as a function of volcanic activity and strong hydroclimate variability.
Against this background, this PhD thesis aims to disentangle the controlling factors that modulate the terrigenous element mobilization and export mechanisms in the hyper-humid Patagonian Andes and assesses their significance for fjord primary productivity over the past 4.5 kyrs BP. For the first time, distinct biogeochemical characteristics of the regional weathering system serve as major criterion in paleoenvironmental reconstruction in the area. This approach includes broad-scale mineralogical and geochemical analyses of basement lithologies, four soil profiles, volcanic ash deposits, the non-karst stalagmite MA1 and two lacustrine sediment cores. In order to pay special attention to the possibly important temporal variations of pedosphere-atmosphere interaction and ecological consequences initiated by volcanic eruptions, the novel data were evaluated together with previously published reconstructions of paleoclimate and paleoenvironmental conditions.
The devastative high-tephra loading of a single eruption from Mt. Burney volcano (MB2 at 4.216 kyrs BP) sustainably transformed this vulnerable fjord ecosystem, while acidic peaty Andosols developed from ~2.5 kyrs BP onwards after the recovery from millennium-scale acidification. The special setting is dominated by most variable redox-pH conditions, profound volcanic ash weathering and intense OM turnover processes, which are closely linked and ultimately regulated by SWW-induced water-level fluctuations. Constant nutrient supply though sea spray deposition represents a further important control on peat accumulation and OM turnover dynamics. These extreme environmental conditions constrain the biogeochemical framework for an extended land-to-fjord export of leachates comprising various organic and inorganic colloids (i.e., Al-humus complexes and Fe-(hydr)oxides). Such tephra- and/or Andosol-sourced flux contains high proportions of terrigenous organic carbon (OCterr) and mobilized essential (micro)nutrients, e.g., bio-available Fe, that are beneficial for fjord bioproductivity. It can be assumed that this supply of bio-available Fe produced by specific Fe-(hydr)oxide (trans)formation processes from tephra components may outlast more than 6 kyrs and surpasses the contribution from basement rock weathering and glacial meltwaters. However, the land-to-fjord exports of OCterr and bio-available Fe occur mostly asynchronous and are determined by the frequency and duration of redox cycles in soils or are initiated by SWW-induced extreme weather events.
The verification of (crypto)tephra layers embedded stalagmite MA1 enabled the accurate dating of three smaller Late Holocene eruptions from Mt. Burney (MB3 at 2.291 kyrs BP and MB4 at 0.853 kyrs BP) and Aguilera (A1 at 2.978 kyrs BP) volcanoes. Irrespective of the improvement of the regional tephrochronology, the obtained precise 230Th/U-ages allowed constraints on the ecological consequences caused by these Plinian eruptions. The deposition of these thin tephra layers should have entailed a very beneficial short-term stimulation of fjord bioproductivity with bio-available Fe and other (micro)nutrients, which affected the entire area between 52°S and 53°S 30´, respectively. For such beneficial effects, the thickness of tephra deposited to this highly vulnerable peatland ecosystem should be below a threshold of 1 cm.
The Late Holocene element mobilization and land-to-fjord transport was mainly controlled by (i) volcanic activity and tephra thickness, (ii) SWW-induced and southern hemispheric climate variability and (iii) the current state of the ecosystem. The influence of cascading climate and environmental impacts on OCterr and Fe-(hydr)oxide fluxes to can be categorized by four individual, in part overlapping scenarios. These different scenarios take into account the previously specified fundamental biogeochemical mechanisms and define frequently recurring patterns of ecosystem feedbacks governing the land-to-fjord mass transfer in the hyper-humid Patagonian Andes on the centennial-scale. This PhD thesis provides first evidence for a primarily tephra-sourced, continuous and long-lasting (micro)nutrient fertilization for phytoplankton growth in South Patagonian fjords, which is ultimately modulated by variations in SWW-intensity. It highlights the climate sensitivity of such critical land-to-fjord element transport and particularly emphasizes the important but so far underappreciated significance of volcanic ash inputs for biogeochemical cycles at active continental margins.
Background: Hyperhidrosis (excessive sweating, OMIM %114110) is a complex disorder with multifactorial causes. Emotional strains and social stress increase symptoms and lead to a vicious circle. Previously, we showed significantly higher depression scores, and normal cortisol awakening responses in patients with primary focal hyperhidrosis (PFH). Stress reactivity in response to a (virtual) Trier Social Stress Test (TSST-VR) has not been studied so far. Therefore, we measured sweat secretion, salivary cortisol and alpha amylase (sAA) concentrations, and subjective stress ratings in affected and non-affected subjects in response to a TSST-VR.
Method: In this pilot study, we conducted TSST-VRs and performed general linear models with repeated measurements for salivary cortisol and sAA levels, heart rate, axillary sweat and subjective stress ratings for two groups (diagnosed PFH (n = 11), healthy controls (n = 16)).
Results: PFH patients showed significantly heightened sweat secretion over time compared to controls (p = 0.006), with highest quantities during the TSST-VR. In both groups, sweating (p < 0.001), maximum cortisol levels (p = 0.002), feelings of stress (p < 0.001), and heart rate (p < 0.001) but not sAA (p = 0.068) increased significantly in response to the TSST-VR. However, no differences were detected in subjective ratings, cortisol concentrations and heart rate between PFH patients and controls (pall > 0.131).
Conclusion: Patients with diagnosed PFH showed stress-induced higher sweat secretion compared to healthy controls but did not differ in the stress reactivity with regard to endocrine or subjective markers. This pilot study is in need of replication to elucidate the role of the sympathetic nervous system as a potential pathway involved in the stress-induced emotional sweating of PFH patients.
Formulations of macrocyclic lactone anthelmintics such as moxidectin are regularly administered to sheep to combat parasites. A disadvantage of these pharmaceuticals are their side effects on non-target organisms when entering the environment. Little is known about anthelmintic effects on plant reproduction and whether the effects depend on environmental factors. For ecological and methodological reasons, we aimed at testing whether temperature affects the efficacy of a common moxidectin-based formulation on seed germination. We carried out a germination experiment including three typical species of temperate European grasslands (Centaurea jacea, Galium mollugo, Plantago lanceolata). We applied three temperature regimes (15/5, 20/10, 30/20°C), and a four-level dilution series (1:100–1:800) of formulated moxidectin (i.e., Cydectin oral drench). These solutions represent seed-anthelmintic contacts in the digestive tract of sheep shortly after deworming. In addition, a control was carried out with purified water only. We regularly counted emerging seedlings and calculated final germination percentage, mean germination time and synchrony of germination. Formulated moxidectin significantly reduced percentage, speed and synchrony of germination. A 1:100 dilution of the formulation reduced germination percentage by a quarter and increased mean germination time by six days compared to the control. Temperature moderated effects of the anthelmintic drug on germination in all response variables and all species, but in different patterns and magnitudes (significant anthelmintic x temperature x species interactions). In all response variables, the two more extreme temperature regimes (15/5, 30/20°C) led to the strongest effects of formulated moxidectin. With respect to germination percentage, G. mollugo was more sensitive to formulated moxidectin at the warmest temperature regime, whereas P. lanceolata showed the highest sensitivity at the coldest regime. This study shows that it is important to consider temperature dependencies of the effects of pharmaceuticals on seed germination when conducting standardised germination experiments.