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Addition of Phosphogypsum to Fire-Resistant Plaster Panels:
A Physic–Mechanical Investigation
(2023)
Gypsum (GPS) has great potential for structural fire protection and is increasingly used in construction due to its high-water retention and purity. However, many researchers aim to improve its physical and mechanical properties by adding other organic or inorganic materials such as fibers, recycled GPS, and waste residues. This study used a novel method to add non-natural GPS from factory waste (phosphogypsum (PG)) as a secondary material for GPS. This paper proposes to mix these two materials to properly study the effect of PG on the physico-mechanical properties and fire performance of two Tunisian GPSs (GPS1 and GPS2). PG initially replaced GPS at 10, 20, 30, 40, and 50% weight percentage (mixing plan A). The PGs were then washed with distilled water several times. Two more mixing plans were run when the pH of the PG was equal to 2.4 (mixing plan B), and the pH was equal to 5 (mixing plan C). Finally, a comparative study was conducted on the compressive strength, flexural strength, density, water retention, and mass loss levels after 90 days of drying, before/after incineration of samples at 15, 30, 45, and 60 min. The results show that the mixture of GPS1 and 30% PG (mixing plan B) obtained the highest compressive strength (41.31%) and flexural strength (35.03%) compared to the reference sample. The addition of 10% PG to GPS1 (mixing plan A) improved fire resistance (33.33%) and the mass loss (17.10%) of the samples exposed to flame for 60 min compared to GPS2. Therefore, PG can be considered an excellent insulating material, which can increase physico-mechanical properties and fire resistance time of plaster under certain conditions.
Properties Evaluation of Composite Materials Based on Gypsum Plaster and Posidonia Oceanica Fibers
(2023)
Estimating the amount of material without significant losses at the end of hybrid casting is a problem addressed in this study. To minimize manufacturing costs and improve the accuracy of results, a correction factor (CF) was used in the formula to estimate the volume percent of the material in order to reduce material losses during the sample manufacturing stage, allowing for greater confidence between the approved blending plan and the results obtained. In this context, three material mixing schemes of different sizes and shapes (gypsum plaster, sand (0/2), gravel (2/4), and Posidonia oceanica fibers (PO)) were created to verify the efficiency of CF and more precisely study the physico-mechanical effects on the samples. The results show that the use of a CF can reduce mixing loss to almost 0%. The optimal compressive strength of the sample (S1B) with the lowest mixing loss was 7.50 MPa. Under optimal conditions, the addition of PO improves mix volume percent correction (negligible), flexural strength (5.45%), density (18%), and porosity (3.70%) compared with S1B. On the other hand, the addition of PO thermo-chemical treatment by NaOH increases the compressive strength (3.97%) compared with PO due to the removal of impurities on the fiber surface, as shown by scanning electron microscopy. We then determined the optimal mixture ratio (PO divided by a mixture of plaster, sand, and gravel), which equals 0.0321 because Tunisian gypsum contains small amounts of bassanite and calcite, as shown by the X-ray diffraction results.
This study scrutinizes press photographs published during the first 6 weeks of the Russian War in Ukraine, beginning February 24th, 2022. Its objective is to shed light on the emotions evoked in Internet-savvy audiences. This empirical research aims to contribute to the understanding of emotional media effects that shape attitudes and actions of ordinary citizens. Main research questions are: What kind of empathic reactions are observed during the Q-sort study? Which visual patterns are relevant for which emotional evaluations and attributions? The assumption is that the evaluations and attributions of empathy are not random, but follow specific patterns. The empathic reactions are based on visual patterns which, in turn, influence the type of empathic reaction. The identification of specific categories for visual and emotional reaction patterns are arrived at in different methodological processes. Visual pattern categories were developed inductively, using the art history method of iconography-iconology to identify six distinct types of visual motifs in a final sample of 33 war photographs. The overarching categories for empathic reactions—empty empathy, vicarious traumatization and witnessing—were applied deductively, building on E. Ann Kaplan's pivotal distinctions. The main result of this research are three novel categories that combine visual patterns with empathic reaction patterns. The labels for these categories are a direct result of the Q-factorial analysis, interpreted through the lense of iconography-iconology. An exploratory nine-scale forced-choice Q-sort study (Nstimuli = 33) was implemented, followed by self-report interviews with a total of 25 participants [F = 16 (64%), M = 9 (36%), Mage = 26.4 years]. Results from this exploratory research include motivational statements on the meanings of war photography from semi-structured post-sort-interviews. The major result of this study are three types of visual patterns (“factors”) that govern distinct empathic reactions in participants: Factor 1 is “veiled empathy” with highest empathy being attributed to photos showing victims whose corpses or faces were veiled. Additional features of “veiled empathy” are a strong anti-politician bias and a heightened awareness of potential visual manipulation. Factor 2 is “mirrored empathy” with highest empathy attributions to photos displaying human suffering openly. Factor 3 focused on the context. It showed a proclivity for documentary style photography. This pattern ranked photos without clear contextualization lower in empathy than those photos displaying the fully contextualized setting. To the best of our knowledge, no study has tested empathic reactions to war photography empirically. In this respect, the study is novel, but also exploratory. Findings like the three patterns of visual empathy might be helpful for photo selection processes in journalism, for political decision-making, for the promotion of relief efforts, and for coping strategies in civil society to deal with the potentially numbing or traumatizing visual legacy of the War in Ukraine.